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Shimizu, M., Science of Synthesis, (2004) 7, 650.
Methylmagnesium carbonate (5) is readily generated by the reaction of magnesium methoxide (2) with carbon dioxide in dimethylformamide (see Section 7.6.13.5).[14,30] This reagent is useful for the carboxylation of a variety of anions (Scheme 10).
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Meeeeee-eeee eeeeeeee ee eeeeeeee eeeeeeeeeee ee eeeeeeee ee eeeeeeeee eeeeeeeee. α-Meeeeeeee (e.e., 88) eeeeeee eeeeeee ee eeeeeeeeeeeeee Meeeeee eeeeeeee ee eeee eeeeeeeeeeee-8,8-eeeeee (e.e., 88) ee eeee eeeeee (Meeeee 88).[88]
Meeeee 8,8-eeeeeeeeeeeeee (88) ee eeeeeeeeeeee eeeeeeee ee eeeeeeee 8-eeeeee-8-eeeeeee-8-eeeeee-8M-eeeee-8-eee (eeeeeeeeeeeee eeee) eeee eeeeeeeee eeeeeeeee ee eeeeeeee.[88]
Meeeee 88 Meeeeeeee Meeeeeeee Meeeeeeee Meeeeeeee[88–88]
Meeeeeeeeeee Meeeeeeee
8-Meeeeeeeeeeeeeeeee-8,8-eeeee (88): [88]
8-Meeeeeeeee-8-eee-8,8-eeeee (88; 8.88 e, 8.8 eeee) ee eee MeMM (88 eM) eee eeeee eeee 88 eee ee e eeeeeeeee eeee ee Me(MMe)8 (8; 8.8 e) ee eee MeMM (888 eM). Meeee eeeeeeeee eee ee eeeeeeeeee 88 eee, eee MeMM eee eeeeeee eeeee eeeeeee eeeeeeee, eee eee eeeeeee eee eeeeeeeee ee Me8M eee eeeeeeeee. Mee eeeeeee eeeee eee eeeeee eeeee eeeeeee eeee eeeee (Me8MM8). Meeeeeeeeee eeee e eeeee eeeee eeeeeeeeeee eeee eeee eee eeeeeeeeeeeeee (Me8M) eee eeeeeee eeeeeeee ee eeeeeeeeeee ee 88°M (8.8 Meee) ee eeee eeeeeeeee eeeeeeee; eeeee: 8.888 e (88%).
References
[14] | Meeeeeeeee, M. M.; Meeeee, M., M. Me. Meee. Mee., (8888) 88, 888. |
[30] | Meeeee, M.; Meeeeeeeee, M. M., M. Me. Meee. Mee., (8888) 88, 888. |
[31] | Me'Meee, M. M.; Meeee, M. M., M. Meee. Mee., (8888), 888. |
[32] | Meeeeee, M. M.; Meeee, M., Meeeeeeeeee, (8888) 88, 8888. |
[33] | Meeeeeee, M.; Meeeeee, M.; Mee Meeeeee, M., M. Mee. Meee., (8888) 88, 8888. |
[34] | Meeeee, M.; Meeee, M., Meee. Mee., (8888) 888, 88. |
[35] | Meeee-Meee, M. M.; Meee, M.; Meeee, M. M.; Meeeee, M. M., M. Mee. Meee., (8888) 88, 8888. |
[36] | Meeee, M.; Meeeee, M. M.; Meeeeee, M. M., M. Me. Meee. Mee., (8888) 888, 888. |
[37] | Meee, M. M.; Meee-Meeeeee, M. M.; Meeeee, M. M., M. Meee. Mee., Meee. Meeeee., (8888), 8888. |
[38] | Meeeeeee, M. M., Meeee. Meeeee., (8888) 8, 88. |