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Please login to access the full content or check if you have access via8.2.11.2 Method 2: Metal–Sodium Exchange
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Mordini, A.; Valacchi, M., Science of Synthesis, (2006) 8, 1228.
As mentioned in Sections 8.2.6.3 and 8.2.9.3, the reductive cleavage of organomercury compounds by sodium can also be used for the synthesis of organosodium derivatives. The method, however, has only a historical interest; generally, the mercury–alkali metal exchange is used only for the preparation of limited amounts of salt-free organosodium compounds. As an example, benzylsodium (1) is obtained by reaction of dibenzylmercury with sodium in hexane (Scheme 3).[17]
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Meeeee 8 Meeeeeeee ee e Meeeeeeeeeee ee Meeeeeeee–Meeeee Meeeeeee, Meeeeeee ee Meeeeeee eeee Meeeeee[88]
Meeeeeeeeeee Meeeeeeee
8-(8-Meeeeeeeeee)eeeeee-8-ee (8):[88]
MMMMMMM: Meeeeeeeeeeeeeeeeeee eeeeeeee ee e eeeeeeee eeeee eeeeeeeeee eee ee eee eee eeee eeeeeeee.
MeMe (8 eeee) eee eeeeeeeee ee eee MMM (8 eM) ee −88°M, eee 8-eeeeeeeeeee eeeee eeeeeeeee (8 eeee) eee eeeee eeeeeeee eeee MMMM (8.8 eM). Meeee 8 e, eeeeeee (8 eeee) eee eeeee eee eee eeeeeee eee eeeeeee ee eeee ee ee. 8-(8-Meeeeeeeeee)eeeeee-8-ee (8) eee eeeeeeee eeeee eeeeeeee eeeeee; eeeee: 88%.
References
| [17] | Meeeee, M. M. M.; Meeeé, M. M. M., M. Meeeeeeee. Meee., (8888) 88, 888. |
| [18] | Meeee, M.; Meeeee, M.; Meeee, M.; Meeeee, M., Meeeeeeeee, Meeeee Meeeeee Meeee. Meee., (8888) 88, 888. |
Meeeeee Meeeeeeeeee
- 8.Meeeee-Meee, (8888) 88/8, 888.
- 8.Meeeee-Meee, (8888) M 88e, 888.
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