Science of Synthesis

Venturello, P.; Barbero, M., Science of Synthesis, (2006) 8, 1432.

On sequential treatment with potassium diphenylphosphide and hydrogen peroxide, 1,1-dichloro-2-phenylcyclopropane (‌87‌) gives the substitution product ‌88‌, probably through an elimination–addition sequence (‌Scheme 44‌).[‌57‌]

‌Meeeee 88‌ Meeeeeee ee e eee-Meeeeeeeeeeeeeeeeeee eeee Meeeeeeee Meeeeeeeeeeeeeeee[‌88‌]

Meeeeeeeeeee Meeeeeeee

(8-Meeeeeeeeeeeeeeeee-8,8-eeee)eee(eeeeeeeeeeeeeeeee) Meeeeee (‌88‌); Meeeeee Meeeeeeee:[‌88‌]

MMMe8 (8.888 e, 8.8 eeee) eee eeeee ee e eeeeeee eeee ee e-MeMM (8.888 e, 8.8 eeee) ee MMMM (88 eM) eeeee M8. Meeee 88 eee, 8,8-eeeeeeeeeeeeeee[8.8.8]eeeeeee (8.888 e, 8.8 eeee) eee eeeee. Meeee 8 e, eee eeeeeee eee eeeeee eeee M8M eee eee eeeee eee eeeeeeeee eeee eeeeeeeee eeeee (ee 88–88°M). Mee eeeeeeee eeeeeee eeeeee eeee eeeeee eeee M8M eee eeeee ee eeee e eeee ee MMMe8.

Me eeee eeee eee eeeee 8,8-eeeeeeee-8-eeeeeeeeeeeeeeeeee (‌88‌; 8.888 e, 8.8 eeee). Mee eeeeeee eee eeeeeee ee ee eee 8 e eee eeee eeeeee eeee M8M, eee eee eeeee eee eeeeeeeee eeee eeeeeeeee eeeee (ee 88–88°M). Mee eeeeeeee eeeeeee eeeeeeee eeee eeeeee eeee M8M, eeeee, eee eeeeeeeeeeee. Mee eeeeeee eee eeeeeeeee ee MM8Me8 (88 eM) eee eeeeeee ee eeeeeeee eeeeeeeeeee eeeeeeee ee 88% ee M8M8 (88 eM) ee eee eeeeeee eeee. Mee eeeeeee eee eeeeeee eee 88 e eee eeee eee eeeeeee eeeee eee eeeeeeeee, eeeeee eeee M8M, eee eeeee. Mee eeeee eeeeeee eee eeeeeeee ee eeeee eeeeee eeeeeeeeeeeeee (eeeeee eee, Me8M/MM8Me8 8:8); eeeee: 8.888 e (88%).

References

Meeeeee Meeeeeeeeee

• 8.Meeeee-Meee, (8888) M 8, 888.