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Please login to access the full content or check if you have access via8.3.6.18.2 Variation 2: Reaction of 6-Halo-5,5-dimethylhex-1-enes with Potassium Diphenylphosphide
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DOI:
10.1055/sos-SD-008-01221
Venturello, P.; Barbero, M., Science of Synthesis, (2006) 8, 1433.
The reaction of 6-halo-5,5-dimethylhex-1-enes with potassium diphenylphosphide provides evidence to support a single-electron transfer (SET) in the reaction of potassium diphenylphosphide with alkyl halides (Scheme 45). Single-electron transfer is the major reaction pathway in the reaction of the hindered alkyl iodide, but is a minor pathway in the reaction of the corresponding bromide and chloride.[58]
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References
| [58] | Meeee, M. M.; Meeeeeeeee, M.; Meeeeeeeee, M. M., M. Mee. Meee., (8888) 88, 8888. |
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