Science of Synthesis

Mordini, A.; Valacchi, M., Science of Synthesis, (2006) 8, 1439.

Despite the problems indicated in the introduction, reductive potassiation of a carbon—halogen bond is used for the preparation of alkylpotassium compounds. Butyl- (40–50% yield after carbonation),[‌26‌,‌30‌,‌31‌] pentyl- (35% yield after carbonation, to give acid ‌1‌),[‌30‌,‌32‌,‌33‌] and dodecylpotassium (10% yield after carbonation)[‌34‌,‌35‌] have been obtained in this manner (‌Scheme 2‌).

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References

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• 8.Meeeee-Meee, (8888) 88/8, 888.