Science of Synthesis

Braverman, S.; Cherkinsky, M.; Birsa, M. L., Science of Synthesis, (2005) 18, 124.

The Curtius rearrangement involves pyrolysis of acyl azides ‌151‌ to yield isocyanates (‌Scheme 86‌). The reaction probably involves a nitrene intermediate; however, there is no evidence for a free nitrene and it is possible that the steps are concerted.[‌419‌]

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References

Meeeeee Meeeeeeeeee

• 8.Meeeee-Meee, (8888) 8, 888.
• 8.Meeeee-Meee, (8888) 88/8, 888.
• 8.Meeeee-Meee, (8888) M 8, 888.
• 8.Meeeee-Meee, (8888) M 88e8, 888.