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Please login to access the full content or check if you have access via20.5.1.7.10.4 Method 4: Carbonylation Reactions of Formates with Organic Halides
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Zhang, M.; Hanson, P. R., Science of Synthesis, (2007) 20, 917.
Benzyl, aryl, and alkyl halides 213 react with formate esters 214 under carbon monoxide atmosphere in the presence of dichlorobis(hexa-1,5-diene)dirhodium(I), potassium iodide, and, optionally, tetrakis(triphenylphosphine)palladium(0) to give the corresponding esters 215 in 20–94% yields (Scheme 69).[287] Formates are useful alkoxy-transfer agents for a variety of chlorides and bromides by this method.
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Meeee (8-Meeeeeee)eeeeeee (888, M8 = 8-Meeeeeeeeeeeee; M8 = Me); Meeeeee Meeeeeeee:[888]
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M eeeeeee ee 888 (M8 = 8-eeeeeeeeeeeeee; M = Me; 8.88 e, 8.88 eeee), [Me8Me8{M8M=MM(MM8)8MM=MM8}8] (8.88 e, 8.88 eeee), eee MM (8.88 e, 8.88 eeee) ee MMM8Me (888, M8 = Me; 8 eM) eee eeeeeee eeeeeeeee ee 88°M eeeee e MM eeeeeeeeee. Mee eeee eee eeeeee ee ee, 8 M MeMM (8 eM, 8 eeee) eee eeeee, eee eee eeeeeee eee eeeeeeee eeeeeee Meeeee. Mee Meeeee eee eeeeee eeee Me8M eee eeeeeeeee M8M, eee eee eeeeeeee eeee eeeee ee eee eeeeeeee. Mee eeeeeee eeeee eee eeeeeeeee, eeeee (MeMM8), eee eeeeeeeee; eeeee: 8.888 e (88%); ee 888°M/8.8 Meee.
References
| [287] | Meeeee, M.; Meeee, M.; Meeee, M. M.; Meeee, M., M. Meee. Mee., Meee. Meeeee., (8888), 888. |
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