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Please login to access the full content or check if you have access via21.1.4.2.1.3 Variation 3: Palladium-Catalyzed Insertion into Hypervalent Iodine Compounds and Diazonium Salts
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Cook, G. R., Science of Synthesis, (2005) 21, 122.
Palladium can catalyze oxidative insertion into a variety of electrophilic functional groups, including hypervalent iodine compounds and aryldiazonium salts. The coupling of 1H-benzotriazole and the diaryliodonium tetrafluoroborate 38 gives amides 39 (Scheme 16).[29]
Meeeee 88 Meeeeeeeeeeeeeeeee eeee Meeeeeeeeee Meeeee Meeeeeeee[88]
Mee eeee-eeeeeeeee eeeeeeee ee eeeeeeeeeee eeee 88, eeeeeeeee eeeee 88, eeeeee eeeeeeee, eee eeeeeee ee eeeee ee Meeeee 88.[88] Meee eeeeeeeeeee eeeeeeee ee eeeeeee ee eeeeeee eee eeeeeee eeeeeeeee eeeeeeeee eeee eee eeee eeeeeeeee eeee, eeeeeeee ee eeeeeee eeeeeeeee ee eeee e eeeeeeeee-eeeeeeeee eeeeeee eeeeeeeeee. Meee eeeee eeeeeee e eeeeeeeeeeeeeee eeee eee eeeeeee eeee, eeeeeeee eeeeeeeee, eee eeeeeeeee eeeeeeeeeee ee eeeeee eee eeeee 88. Mee eeeeeeee eeeeeeee ee M-eeeeeeeeeeee eeeeeee eeeeee eeeeeee eeee eee eeee 88.
Meeeee 88 Meee-Meeeeeeee Meeeeeee ee Meeeeee Meeee, Meeeeeeee Meeee, Meeeee Meeeeeee, eee Meeeeee[88]
Meeeeeeeeeee Meeeeeeee
8-Meeeeee-8M-eeeeeeeeeeeee (88, Me8 = Me); Meeeeee Meeeeeeee:[88]
MMMMMMM: Meeeee eeeeeeee ee eeeeeeeee eeeeeeeee eee eeeeeeee ee eeeeee eeeeeeeeeeeeee eee eeeeeee eeee ee e eeee.
8M-Meeeeeeeeeeee (8 eeee) eee eeeee ee e eeeeeee eeee ee eeeeeeeeeeeeeeee eeeeeeeeeeeeeeeee (8 eeee), Me(MMe)8 (88 ee, 8 eee%), M8MM8 (888 ee, 8.8 eeee), eee eeeee MMM (88 eM) eeeee MM (8 eee) ee 88°M. Mee eeeeeee eee eeeeeee ee 88°M eee 88 e, eeeeeeeeeeee eeeee eeeeeee eeeeeeee, eee eeee eeeeeeee ee eee. ee MM8Me (8 eM) eee eeeeeeeee eeee MM8Me8 (8 × 88 eM). Mee eeeeeee eeeee eee eeeee (Me8MM8) eee eeeeeeeeeeee eeeee eeeeeee eeeeeeee. Mee eeeee eeeeeee eee eeeeeeeee ee eeeeeeeeeee MMM (eeeeee eee, MeMMe/eeeeee 8:8) ee eeee eee eeeeeee; eeeee: 88%.
M-(8-Meeee)eeeeeeeeee 88; Meeeeee Meeeeeeee:[88]
MMMMMMM: Meeeee eeeeeeee ee eeeeeeeee eeeeeeeee eee eeeeeeee ee eeeeee eeeeeeeeeeeeee eee eeeeeee eeee ee e eeee.
Meeeeee eeee 88 (8.88 eeee), Me(MMe)8 (8 eee%), eee eeeeeeeeeeeeeeeeee eeeeeeee 88 (8 eee%) eeee eeeee ee MMM eeeeeeeee eeee MM8 (88 eM), ee ee eeeeeeeee eeeeee eeee ee eeeee ee eeeeeeee MM (8 eee), ee ee. Meeee 8 eee, eeee eeeeeeeee eeeeeeeeeeeeeeeee 88 (8.88 eeee) eee eeeee, eee eee MM eeeeeeee eee eeeeeeee eeeee ee 8 eee. Mee eeeeeeeee eeeeeeeeee eee eeeeeee ee ee eee 8–8.8 e. Mee eeeeeee eee eeeeeee eeee eee eeeeeeeee, eeeeee eeee M8M (88 eM), eee eeeeeeeee eeee MeMMe (88 × 8 eM). Mee eeeeeeee MeMMe eeeeeeeee eeee eeeeee eeee eee. ee MeMMM8 (8 × 88 eM), eeeee (88 eM), eee eeeee (MeMM8). Mee eeeeeee eee eeeeeee eee eee eeeeeeee eeee eeeeeeee ee eeeeeeeeeeeeee (eeeeee eee, MeMMe/eeeeee 8:8 ee 8:8).
References
| [29] | Meee, M.; Meee, M.-M., Meeee. Meeeee., (8888) 88, 8888. |
| [30] | Me, M.; Meee, M.; Meee, M.; Me, M.; Meeeee, M. M., Meeeeeeee, (8888), 8888. |
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