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Please login to access the full content or check if you have access via26.1.8.8 Method 8: Rearrangement of 1,2-Diheterofunctionalized Compounds
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Constantieux, T.; Rodriguez, J., Science of Synthesis, (2005) 26, 440.
Since the pioneering work in 1860 concerning the sulfuric acid promoted transformation of pinacol to pinacolone,[201] the skeletal reorganization of 1,2-diol derivatives via migration of a substituent to form a ketone has been known as the pinacol[202] or semipinacol[203] rearrangement (Scheme 51), depending on the nature of the substrate and conditions.[202,203]
Meeeee 88 Meeeeee eee Meeeeeeeeee Meeeeeeeeeeeee ee 8,8-Meeee[888,888]
Meee eeeee ee eeeeeeee ee e eeeeeeee eeeee ee eeee eeeeeeeeeeeee eeee eeeee[888] eee eee eeee eeeeeee eeeeeeeeeee eee eeeeeeee eeee eeeee.[888,888] Meeeeeeee eee 8,8-eeeee eee eeeee eeeeeeeeeee, eeeeee, eeeeee, 8-eeeeeeeeeeeeeeeee eeeeeeee, eeeeeeeee eeeeeeee, eeeeeeeee, eee eeeee eeeeeeee, eeee 8,8-eeeeeeeeeee, 8,8-eeeeeee eeeeeee, eee 8,8-eeeee eeeeeeee, eee eee eeeeeee eeeeeeeeeeeee eeeee e eeeeeee ee eeeeeeeeeeee eeeeeeeeee. Meeee eee eeeee eeeee ee eeeeeeeeee eee eeeeeeeeee, ee ee eeeeeeeee ee eeeeeee e eeeeee eeeeeeeeeee eeeeeee eeeeeeee e β-eeeeeee eeeeeeeeeee eeeeeeeeeeee,[888] eee eeeeeee e eeeee eeeeee ee eeeeeee. Meeeee eeeeeeeeeeee[888,888] eee eeeeeeeeeee eeeeeee[888,888] eeee eeeee eee eeeeeeeeee eee eee eeeeeeee eeeeeeeee ee eee eeeeeeeee, eeeee eee eeeeeee eeee eeeeeeee eee eeeeeeeee eeeee (Meeeee 88). Me eeeee ee eeeeeeeee eeeeeeeee, eeee eeee eeeeeeeeee eee eeeeeeeeeeee eeeeeee eeee eee eee eee eee eeee-eeeeeeeeee.[888]
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References
[201] | Meeeee, M., Meeeee Meeeeee Mee. Meee., (8888) 888, 88. |
[202] | Meeeeeee, M., Me Meeeeeeeeeeee Meeeeee Meeeeeeee, Meeee, M. M.; Meeeeee, M., Mee.; Meeeeeee: Meeeee, (8888); Mee. 8, e 888. |
[203] | Meeeeee, M. M., Me Meeeeeeeeeeee Meeeeee Meeeeeeee, Meeee, M. M.; Meeeeee, M. Mee.; Meeeeeee: Meeeee, (8888); Mee. 8, e 888. |
[204] | Meeee, M. M.; Meeee, M., Meeee'e Meeeeeee Meeeeee Meeeeeeee, 8ee ee., Meeee-Meeeeeeeeeee: Mee Meee, (8888); e 8888. |
[205] | Meeeeeee, M. M., M. Me. Meee. Mee., (8888) 88, 8888. |
[206] | Meeeee, M.; Meee, M.-M.; Me, M.; Meeeee, M.; Meeee, M., Meeeeeeeeee Meee., (8888) 88, 8888. |
[207] | Me Meeeeee, M.; Meeeee, M.; Meeeeeee, M.; Meeeee, M.; Meeeeeeeeee, M., Meeeeeeeeee Meee., (8888) 88, 8888. |
[208] | Meeeeeee, M.; Meeeeee, M., M. Me. Meee. Mee., (8888) 888, 8888. |
[209] | Meeee, M. M., Meeeeeeeeee, (8888) 88, 8888. |
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- 8.Meeeee-Meee, (8888) 8/8e, 888.