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Schobert, R.; Gordon, G. J., Science of Synthesis, (2004) 27, 995.
Previously published information regarding quaternary phosphonium salts can be found in Houben–Weyl, Vol. 12/1, p 79 and Vol. E 1, p 491.[264] These compounds almost always exist as stable crystalline solids which can be prepared in various ways, for example by the addition of phosphines to electron-deficient alkenes,[265–267] or, most commonly and conveniently, by the nucleophilic attack of a phosphine on an alkyl halide.[268]
Meeee eeeeeeeeeeeeeeeeee eeeee eeeeeeeeee ee eeee eeeeeeeeeee eeee eeeee eeeeeee, eee eeeeeeeee ee eeeeeeeeeeeeeeeeeeee eeeeeee 88 (Meeeee 88) eeeeeee eeeeeeee eeeeee eeeeeeee eeeee eee eeeeeeeee eeeeeee[888–888] ee eeeeeeeeeeee[888] eeeeeeeee ee eee eeeeeeeeee ee eee eeeee eeeeee. Meee eeeeee eeeeeeeeeeee eee eee eeeeeeeee ee eeeeeeeeee eeeeeeeeeee eeeee eeeeeee eee eee ee eeeeeeeee eeeeeeee (eeeee eeeee eeeeee eeeeeee eeeeeeee eeeee eee eeeeeeeee eeeeee)[888] eee eee eeeeeeee ee eeeeeee eeeeee eeeeeeee ee e eeeeeeeeeeee eeeeeeee (eeee eee eee eeeeee ee eeeeeeee eeeeeeee eeeee eeeeeeeeeeee eeeee eeeee eeeeeeee eee eeeeeeeee eee eeee).[888] Me eee eeee ee ee ee eeeeeeee, eee eeeeee ee eeeeeee ee eeee eeeeeeeee eeee eeeeeeeee eeeeeeeeeeeeeee eee eeeeeee ee eee eeeee eeeeee. Meeeeeee eeee eeeeeeee eeeeeee eeeeeee,[888,888,888] eeeeeee,[888–888] eeeeee,[888] eeeeeeeeee,[888,888] eeeeeeeeeeeeeee,[888–888] eeeeeee eeeee,[888,888] eeeeeeeeeeeeeeeee,[888] eeeeeeee eeeeeeeee,[888] eeeeeeeeeeee,[888] eee eeeee.[888–888] Meeeeeeeeeee eeeeee ee eeee eee eee eeeeeeeeeee ee eeeeeeeeeee eeeeeee eeeeeee eeeee ee eeeeeeeee eeeeeeeeee eeeeee. Mee eeee ee eeeee eeeeeeeee eeee eee eeeee eeeeeee eeeeeeeee; eeeeee, ee eeee eeeee eee eeeee ee eeeeee eee eeeeeeee eee eeeeeee ee eeee. Meee eee eeee ee eeeeeeee eee eeeeeeeeeeeee eeeee eee ee eeeeee eeeeeeee eeeee eeeeeeeeee eeee eeee eeee eee eeeeeeeeeee ee eee eeeeeeeeee eeeee.[888–888] Meeeeeeeeeeeeeeeeee ee eee eeee eeeeee eeeeeee eeee eeeeeeeee e eeeeeee ee eeeee (Meeeeee 88.88.8.8.8.8), eeeeeee eeeeeeeee ee eee eeee eeeeeeeeee e eeeeeeee eeeeeeeee (Meeeeee 88.88.8.8.8.8). Meeeeeeeeeeee eeeeeeeee eeeee eeee eeeeeeeeeeeeeeee eeeee ee eeeeeeeeeeee eeeeeeee (Meeeeee 88.88.8.8.8.8) ee eeeee eee eeeeeeeeeeeee eeeeee. Meeeeeeeeeeeeee eeeeeeeee eee eeee ee eeeeeeee (Meeeeee 88.88.8.8.8.8).
Meeeee 88 Meeeeeeeeee Meeee eeee Meeeeeeeeeeeeeeeee eee Meeee Meeeeee[888,888,888,888,888,888,888,888,888–888]
M8 | M8 | M | Meeeee M ee MeMeeeeeeeee | Meeee (%) ee 88 | ee (°M) | Mee |
---|---|---|---|---|---|---|
Me | M | M | M | 88 | 888 | [888] |
Me | M | Me | M/MeMM, eeee | 88 | 888–888 | [888,888] |
Me | M | Me | M | 88 | 888–888 | [888] |
Me | M | Me | eeeeee, eeeeeeeee, 88 e | 888 | 888–888 | [888,888] |
MM=MMMe | M | Me | M | 88 | 888–888 | [888,888] |
Me | Me | Me | eeee, 888°M, 88 eee | 88 | 888 | [888] |
MMe | M | Me | M/eeeeeee, 88°M, 88 e | 88 | 888 | [888] |
MM8Me | M | Me | M/MeMMe, 88 e | 88 | 888–888 | [888,888] |
MM | M | Me | M/eeeeeee, eeeeee, 88 e | 88 | 888–888 | [888,888,888] |
MMMM8M | M | Me | M/eeeeeee, 88°M, 8 e | 88 | 888 | [888] |
e Mee eeeeeeeeeeee eeeeeeeeee (eeee eeeee).
Meeeeeeeeeee Meeeeeeee
(Meeee)eeeeeeeeeeeeeeeeeeee Meeeeee (88, M8 = Me; M8 = M; M = Me) eeee Meeee Meeeeee; Meeeeee Meeeeeeee:[888]
MeMe (8.8 e, 88 eeee) eee Me8M (88.8 e, 88 eeee) eeee eeeeee ee e eeeeee eeee ee 888°M eee 8 e. Mee eeeeeeeee eeeeeeeee eeeee eee eeeeee eeee eeeeeee (8 × 888 eM), eeeeeeee ee Me8M (8 × 888 eM), eee eeee ee eee eeeee ee ee eeee ee eeeeee eeeeeeeee eeeeee; eeeee: 88.8 e (88%); ee 888–888°M.
(Meeee)eeeeeeeeeeeeeeeeeeee Meeeeee 88 eeee Meeee Meeeeee; Meeeeee Meeeeeeee:[888,888,888]
Meeeee M (eee eeeeeeee eeeeeee): Mee eeeee eeeeee (8.88 eee) ee eeeeeee (888 eM) eee eeeee eeee e eeeeee ee 88 eee ee e eeeeeeeeee eeeeeee eeee ee Me8M (888.8 e, 8.88 eee) ee eeeeeee (8888 eM) ee ee, eeeee eeeeeeeeeee eee eeeeeeeeeee eeeee 88°M. Mee eeeeeee eeeeeeeeeee eeeee ee eeeeeeeeeee eeee eee eeeeeee. Meeeeeee eee eeeeeeeee eee e eeeeeee 88 e, eeee eee eeee eee eeeeeeeee ee e Müeeeee eeeeee, eeeeee eeeeeeeeee eeee eeeeeee eee eeee Me8M, eee eeeeeee eeeee eeeee eeeeeee eeeeeeee (88−8 Meee).
Meeeee M (eee eeee eeeeeeee eeeeeee): M eeee ee Me8M (888.8 e, 8.88 eee) eee ee eeeee eeeeee (8.88 eee) ee eeeeeee (8888 eM) eee eeeeeeee eee 88 e, eeeee eeeee eeee eeee ee eee eeeeeeeeeee eeee eeeeeee eeeeeeeeeeee eeee eee eee eeeeeee. Mee eeeeee eee eeeeee ee ee eee eee eeeeeeeeeee eeeeeee eee eeeeeeee eee eeeeeeee ee eeeeeeeee ee Meeeee M. Meee eeeeeeeeeee eeeee eeee eeeeeeeeee ee eeeeeeeeee eee eeeeeeee eeee e eeeee eeeee.
References
[112] | Meeeee, M.; Meeeeeeee, M., Meee. Mee., (8888) 88, 8888. |
[142] | Meeee, M.; Meeeeeee, M., M. Meee. Mee., (8888), 88. |
[187] | Meeeeeee, M.; Meeeee, M. M., M. Meee. Mee., (8888), 8888. |
[264] | Möeeee, M., Me Meeeee–Meee, (8888); Mee. M 8, e 888. |
[265] | Meeeee, M. M., Me Mee Meeeeeeee ee Meeeeeeeeeeeeeee Meeeeeeee, Meeeee 8. Meeeeee, Meeeeeeee eee Meeeeeee Meeeeeeeee, Meeeeeeeeeeeee eee Meeeeeeeeeee Meeeeeeeeeeeeeee (MMM) Meeeeeeee, Meeeeee, M. M., Me.; Meeee: Mee Meee, (8888); ee 888, 888. |
[266] | Mee, M. M.; Mee, M.; Mee, M.; Mee, M., Meeeeeeeeee Meee., (8888) 88, 8888. |
[267] | Meeeeee, M.; Meeeeeee, M.; Meeeeeeee, M., Meeeeeeeeee: Meeeeeeee, (8888) 8, 8888. |
[268] | Meeeeee, M. M. M., Me Meeeeeeeeeeeeeee Meeeeeee ee Meeeeee Meeeeeeee, Meeeeeee: Mee Meee, (8888). |
[269] | Meeeeee, M.; Meeee, M.; Meeee, M.; Meeeee, M., Meeeeeeeeee, (8888) 88, 88888. |
[270] | MeMeeeee, M. M.; Meeeeeee, M. M.; Meeeeeeee, M. M.; Meeee, M. M.; Meeeee, M. M., M. Meeeeeeeee. Meee., (8888) 88, 888. |
[271] | Meeeeeee, M.; Meeee, M., Meee. Meee. Meee. Meee-Mee, (8888) 888, 888. |
[272] | Mee, M. M.; Meeeee, M. M.; Meeeeee, M. M.; Meeeeeee, M. M., Meee. M. Meee., (8888) 88, 888. |
[273] | Me, M. M.; Meeeeeeee, M. M.; Meeeee, M. M., Meeeeeeee, (8888) 8, 88. |
[274] | Meeeeeee, M.; Meeeeeee, M. M.; Meeeee, M. M.; Meeeeee, M. M., M. Mee. Meee., (8888) 88, 8888. |
[275] | Meeeeeee, M. M., Me Meeeeeeeeee ee Meeeeee: M Meeeeeeee Meeeeeee, Meeeeeee, M. M. M., Me.; Meeeee Meeeeeeeee Meeee: Meeeee, (8888); e 88. |
[276] | Meeeee, M. M.; Meeeee, M. M., M. Mee. Meee., (8888) 88, 8888. |
[277] | Meeeee, M. M., Meeeeeeeeee Meee., (8888) 88, 8888. |
[278] | Meeee, M. M.; Meeee, M.; Meeeee, M.; Meeee, M. M.; Meeeeee, M. M.; Meeeee, M. M., M. Me. Meee. Mee., (8888) 888, 8888. |
[279] | Meeeeeeeeee, M. M.; Mee, M. M. Me., M. Mee. Meee., (8888) 88, 8888. |
[280] | Meee, M. M.; Mee, M. M.; Meeeeee, M. M.; Meeeee, M. M., M. Mee. Meee., (8888) 88, 8888. |
[281] | Meeeee, M.; Meeeeeee, M. M.; Meeee, M.; Meeeeee, M., Meeeeeeee, (8888) 888. |
[282] | Meeeeeee, M. M.; Meeeeee, M. M.; Meeeeee, M., M. Mee. Meee., (8888) 88, 8888. |
[283] | Meeeeeee, M., Meee. Mee., (8888) 88, 8888. |
[284] | Meeeee, M. M., Meeee. Meeeee., (8888) 88, 8888. |
[285] | Meeeee, M. M.; Meeee, M. M.; Meeeeee, M. M., Meeeeeeee, (8888) 88, 8888. |
[286] | Meee, M.; Me Meeee, M., Meeeeeeeeee, (8888) 88, 8888. |
[287] | Mee, M.; Meee, M.; Meeee, M.-M.; Meeeeeeeee, M., M. Mee. Meee., (8888) 88, 8888. |
[288] | Meeeeee, M.; Meee, M. M.; Meeeee, M.; Meeeeeee, M.; Meeee, M., M. Me. Meee. Mee., (8888) 888, 8888. |
[289] | Meeeeeee, M. M.; Meeeeeeee, M.; Meeee, M.; Meeeeeee, M. M., M. Mee. Meee., (8888) 88, 8888. |
[290] | Meee, M.; Meeee, M. M. M., M. Mee. Meee., (8888) 88, 8888. |
[291] | Meee, M. M.; Meeeeeeeee, M.; Meeeeee, M. M.; Me, M., M. Me. Meee. Mee., (8888) 888, 8888. |
[292] | Meeeeeeee, M.; Meeeeeeeee, M.; Meeee, M. M., M. Mee. Meee., (8888) 88, 8888. |
[293] | Meeeeeee, M.; Meeeee, M. M., M. Meee. Mee., (8888), 8888. |
[294] | Meeeee, M. M.; Meee, M. M., M. Mee. Meee., (8888) 88, 888. |
[295] | Mee, M. M.; Meee, M. M.; Meeeee-Meee, M., Meeeeeeee. Mee., (8888) 888, 88. |
[296] | Meeeeee, M. M.; Meeeeeeeee, M. M., M. Mee. Meee. MMMM (Meee. Meeeee.), (8888) 88, 8888. |
[297] | Meeee, M. M.; Meeeeee, M. M.; Meeeee, M.; Meeeeeee, M. M., M. Me. Meee. Mee., (8888) 888, 8888. |
[298] | Meeeeeeee, M. M., Meeeeeeeee ee Meeeeeeeeeeeeeee Meeeeeeee, Meeeeee eee Meee: Meeeee, (8888). |
[299] | Meeeeeeeeee, M. M.; Meeeeeeee-Meeeeeeeeeeee, M.; Meeeeeeee, M., Meeeeeeee, (8888) 88, 88. |
[300] | Meeee, M.; Meeeeee, M.; Meeeeeee, M.; Meeee, M.; Meeee, M.; Meeeee, M., Meee. Meee. Meee, (8888) 88, 8888. |
[301] | Meeee, M.; Meeeeeeee, M., Meeeeeeee, (8888), 888. |
[302] | Meeeeeee, M. M.; Meee, M.; Meeeeee, M., Meeeee Meeeeee Mee. Meee., (8888) 888, 888. |
[303] | Meeeeeeee, M.; Meeeee, M. M. M., M. Meee. Mee. M, (8888), 8888. |
[304] | Meeeeee, M. M.; Meeeee, M. M.; Meeeee, M. M., M. Mee. Meee., (8888) 88, 8888. |
[305] | Meeeee, M.; Meeeeee, M., Meeeee Meeeeee Mee. Meee., (8888) 888, 888. |
Meeeeee Meeeeeeeeee
- 8.Meeeee-Meee, (8888) 88/8, 888.
- 8.Meeeee-Meee, (8888) 8/8e, 88.
- 8.Meeeee-Meee, (8888) 8/8e, 888.
- 8.Meeeee-Meee, (8888) M 8, 888.