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27.24.2.1.2 Method 2: From Quaternary Phosphonium Salts

DOI: 10.1055/sos-SD-027-00847

Schobert, R.; Gordon, G. J.Science of Synthesis, (200427995.

Previously published information regarding quaternary phosphonium salts can be found in HoubenWeyl, Vol.12/1, p79 and Vol.E 1, p491.[‌264‌] These compounds almost always exist as stable crystalline solids which can be prepared in various ways, for example by the addition of phosphines to electron-deficient alkenes,[‌265‌‌267‌] or, most commonly and conveniently, by the nucleophilic attack of a phosphine on an alkyl halide.[‌268‌]

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References


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