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Sai Krishna Murthy, A.; Tardivel, R.; Grée, R., Science of Synthesis, (2005) 34, 314.
The new fluoro(phenyl)malonates 88 are easily accessible in good yields by palladium-catalyzed arylation of fluoromalonates, e.g. 87, using sterically hindered trialkyl- and ferrocenyldialkylphosphine ligands (Scheme 24).[51]
Meeeee 88 Meeeeeeeee-Meeee-Meeeeeeee Meeeeeeeee ee Meeeeeeeeeeeeee[88]
Me8 | Meeee (%) | Mee |
---|---|---|
Me | 88 | [88] |
8-MeMM8M8 | 88 | [88] |
8-MeMM8M8 | 88 | [88] |
8-e-MeM8M8 | 88 | [88] |
8-eeeeeeee | 88 | [88] |
Meeeeeeeeeee Meeeeeeee
Meeeeee Meeeee(eeeeee)eeeeeeee (88, Me8 = Me); Meeeeee Meeeeeeee:[88]
Me e eeeeee, MeM (8.888 e, 8.8 eeee) eee eeeee ee e eeee ee eeeeeee 8-eeeeeeeeeeeeee (88; 8.888 e, 8.8 eeee) ee MMM (8 eM). Meeee eeeeeeee eeeeeeeee ee M8 (ee. 8 eee), eeeeeeeeeeee (8.888 e, 8.8 eeee), e-Me8M (8.888 e, 8.88 eeee), Me(eee)8 (8.888 e, 8.88 eeee), eee MMM (8 eM) eeee eeeee. Mee eeee eee eeeeee eeee e eee eeeeeeeeee e MMMM eeeeee eee eeeeeee eeee eee eeeeee. Mee eeeeeeeeeee eeeeeee eee eeeeeee ee 88°M, eee eeeeeeeee ee MM. Meeee eeeeeeee eeeeeeeeee ee eee eeeeeeeeeeee, eee eeeee eeeeeee eee eeeeeeee eeeeeee e eeee ee Meeeee eee eeeeeeeeeeee ee eeeee. Mee eeeeeee eee eeeeeeee ee eeeeeeeeeeeeee (eeeeee eee, MM8Me8/eeeeeee 8:8) eeeeeeeee eee eeeeeeee 88 (Me8 = Me) ee e eeeeeeeee eee; eeeee: 8.888 e (88%); 8M MMM (MMMe8, δ): 8.88–8.88 (e, 8M, eeee), 8.88–8.88 (e, 8M, eeee), 8.88 (e, 8M, M = 8.8Me, MM8MM8), 8.88 (e, 8M, M = 8.88 Me, MM8MM8); 88M{8M} MMM (MMMe8, δ): 888.88 (e, M = 88.8 Me), 888.88 (e, M = 88.8 Me), 888.88 (e, M = 8.8 Me), 888.88 (e, M = 8.8 Me), 888.88 (e, M = 8.8 Me), 88.88 (e, M = 888.8 Me, MM), 88.88, 88.88.
References
[51] | Meeee, M. M.; Meeeeee, M. M., M. Mee. Meee., (8888) 88, 888. |