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Rück-Braun, K.; Freysoldt, T., Science of Synthesis, (2007) 35, 514.
Lithium tetrabromonickelate(II) in tetrahydrofuran offers a soft nucleophilic bromine and is therefore able to open epoxides 47 to bromo alcohols 48 and 49 without attacking other acid- or base-sensitive groups (Scheme 19).[51] There are very few examples for the use of lithium tetrabromonickelate(II) in the literature, yet some natural products can be synthesized using this method.
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References
| [51] | Meee, M. M.; Meeeeeee, M. M.; Meeeee, M. M., Meeeeeeeeee Meee., (8888) 88, 8888. |
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