Science of Synthesis

Chemler, S. R., Science of Synthesis, (2009) 40, 1278.

2,4-Di-tert-butyl-6-methyl-N-thiosulfinylaniline (‌27‌) has been synthesized in very good yield by condensation of 2,4-di-tert-butyl-6-methylaniline (‌26‌) with sulfur monochloride (‌Scheme 14‌).[‌55‌] However, the reaction is not general, and other anilines either do not provide the N-thiosulfinylarylamines or provide them in low yields along with other compounds.

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References

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• 8.Meeeee-Meee, (8888) M 88-8, 888.