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46.5.6 s-trans-Heteroannular 1,3-Dienes

DOI: 10.1055/sos-SD-046-00090

Gandon, V.; Thorimbert, S.; Malacria, M.Science of Synthesis, (200946232.

s-trans-Heteroannular 1,3-dienes may be prepared by various methods including thermal[‌194‌] or microwave-assisted cycloadditions[‌195‌] of allenynes. Metal-mediated cycloadditions of allenynes or dienynes are also possible employing molybdenum,[‌85‌] platinum,[‌177‌,‌178‌] or gold complexes.[‌196‌,‌178‌]