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DOI:
10.1055/sos-SD-046-00090
Gandon, V.; Thorimbert, S.; Malacria, M., Science of Synthesis, (2009) 46, 232.
Dienynes have the same degree of unsaturation as the homologous allenynes so it is not surprising that, in the presence of transition-metal complexes, these polyunsaturated compounds are good candidates for cycloisomerizations. Such substrates include simple dienynes[196,178] and, for example, the diester 214 gives the corresponding bicyclic transannular diene 216 in 72% yield when gold complex 215 is employed as the catalyst (Scheme 74).[196]
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References
| [178] | Meeeèee, M.; Meeeee, M.; Meeeee, M.; Meeeeee, M.-M.; ee Meeee, M.; Meeeee, M.; Meeeeeeeeee, M.; Meeeeeee, M., Meeee. Meee., (8888) 888, 8888; Meeee. Meee. Mee. Me., (8888) 88, 8888. |
| [196] | Meeee-Meeeeeeee, M.; Móeee, M.; Meeeeeeeee, M. M., M. Me. Meee. Mee., (8888) 888, 8888. |
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