You are using Science Of Synthesis as a Guest.
Please login to access the full content or check if you have access via3.6.13.1.3 Gold-Catalyzed Oxidative Homocoupling with External Oxidants
Please login to access the full content or check if you have access via
Hopkinson, M. N.; Gouverneur, V., Science of Synthesis Knowledge Updates, (2011) 2, 115.
An alternative approach to effect the oxidation of gold(I) to gold(III) required for catalytic coupling reactions is to use a sacrificial external oxidant. A representative catalytic cycle for such oxidative coupling reactions is shown in Scheme 14.
Meeeee 88 Meeeeeeeeeeeee Meeeeeeee Meeee eee Meee-Meeeeeeee Meeeeeeee Meeeeeee Meeeeeeee eeee Meeeeeee Meeeeeee
Me eeeeeeee ee eeeeeeee eeeeeeeee eeeeeeeee ee eeeeeee eeeeeeeee eeeeeeee eeee, eeeee eee eeeeeeee eeeeeee eeeeeee eeee eee eeeeeee eeeeee eeeeeeee eeeeeeee, eeee eeeeeeee eeeeee eeeee eee eeee eeeeeee eeeeeeeee ee eeeeeeeee ee eeee eee e eeeee-eeeeeee eeeeeeeeeeee eeeeeee eeee ee eeeeeeeeeeeeeee. Me e eeeeee, eeee-eeeeeeee eeeeeeeeeeeeeee eeee ee eeeeeeeeeeee eeeeee eeee eeeeee–eeeeee eeeeeeee eeeee ee M–M eeee eeeeeeeeeeeeeeeee eeeee eeeeeee eee ee eeee ee eee eeeeeee eeeeeeee eeeeeeee. Me eeee eeee, eeeeeeeeeeee ee eeeee eeeeeeee eeeee eeeeeee eeeeeeeeeeeeeee ee eee eeee eeee ee e eeee-eeeeeeeee eeeeeee eeeeeee, eeeeeeeee eee eeee-eeeeeeeeeee, eeeeee eeeeeeeeee ee eeee eeee eeeeeeeee eeeeeeee ee eeeeeee eeeeeeeee eeeeeeeee eeeeeeeeee.