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3.6.13.1.3 Gold-Catalyzed Oxidative Homocoupling with External Oxidants

DOI: 10.1055/sos-SD-103-00038

Hopkinson, M. N.; Gouverneur, V.Science of Synthesis Knowledge Updates, (20112115.

An alternative approach to effect the oxidation of gold(I) to gold(III) required for catalytic coupling reactions is to use a sacrificial external oxidant. A representative catalytic cycle for such oxidative coupling reactions is shown in Scheme 14.

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