Science of Synthesis

Tobrman, T., Science of Synthesis Knowledge Updates, (2024) 1, 133.

General Introduction

This review builds on the previous contributions in Science of Synthesis devoted to phospholes (Sections 9.14 and 9.14.4).[‌1‌,‌2‌] By following the logical organization of these chapters, the present review summarizes the developments in the preparation of substituted 1H-phospholes reported in the period 2013–2022. The chapter is divided into several sections, including the synthesis of phospholes by ring-closure reactions (Section ‌9.14.5.1.1‌) and the synthesis of 1H-phospholes by ring modifications (Section ‌9.14.5.1.2‌). The preparation of phospholide ions is covered in Section ‌9.14.5.2‌, and the last part (Section ‌9.14.5.3‌) describes advances in the synthesis of η5-phospholyl complexes.

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References