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9.14.5 Phospholes (Update 2024)

DOI: 10.1055/sos-SD-109-00525

Tobrman, T.Science of Synthesis Knowledge Updates, (20241133.

General Introduction

This review builds on the previous contributions in Science of Synthesis devoted to phospholes (Sections 9.14 and 9.14.4).[‌1‌,‌2‌] By following the logical organization of these chapters, the present review summarizes the developments in the preparation of substituted 1H-phospholes reported in the period 2013–2022. The chapter is divided into several sections, including the synthesis of phospholes by ring-closure reactions (Section and the synthesis of 1H-phospholes by ring modifications (Section The preparation of phospholide ions is covered in Section, and the last part (Section describes advances in the synthesis of η5-phospholyl complexes.

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